# Supplementary Material (ESI) for Chemical Communications
# This journal is © The Royal Society of Chemistry 2003

data_global

_journal_coden_Cambridge         182

loop_
_publ_author_name
'J. Escudie'
'C. Couret'
'El Kettani,S. Ech-Cherif'
'Heinz Gornitzka'
'M. Lazraq'
'G. Cretiu Nemes'
'H. Ranaivonjatovo'
'Mohammed Soufiaoui'

_publ_contact_author_name        'Dr J Escudie'
_publ_contact_author_address     
;
Heterochimie Fondamentale et Appliquee
Universite Paul Sabatier
118 Route de Narbonne
Toulouse
Cedex 04
31062
FRANCE
;

_publ_contact_author_email       ESCUDIE@CHIMIE.UPS-TLSE.FR

_publ_requested_journal          'Chemical Communications'

_publ_section_title              
;
The use of a germene for the synthesis of esters of
alpha-germyl-substituted alpha-amino acid and alpha-aminophosphonic acid
;

data_4
_database_code_CSD               207496

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C45 H51 Ge N O3'
_chemical_formula_weight         726.46

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   11.9777(7)
_cell_length_b                   12.1155(7)
_cell_length_c                   14.5540(8)
_cell_angle_alpha                101.8250(10)
_cell_angle_beta                 95.7740(10)
_cell_angle_gamma                108.6110(10)
_cell_volume                     1927.47(19)
_cell_formula_units_Z            2
_cell_measurement_temperature    193(2)
_cell_measurement_reflns_used    9351
_cell_measurement_theta_min      2.464
_cell_measurement_theta_max      29.339

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.5
_exptl_crystal_size_mid          0.7
_exptl_crystal_size_min          0.7
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.252
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             768
_exptl_absorpt_coefficient_mu    0.835
_exptl_absorpt_correction_type   SEMI-EMPIRICAL
_exptl_absorpt_correction_T_min  0.760492
_exptl_absorpt_correction_T_max  1.000000
_exptl_absorpt_process_details   'SADABS (Bruker-AXS)'

_exptl_special_details           
; 
? 
;

_diffrn_ambient_temperature      193(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker CCD detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            12972
_diffrn_reflns_av_R_equivalents  0.0247
_diffrn_reflns_av_sigmaI/netI    0.0428
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_theta_min         1.45
_diffrn_reflns_theta_max         29.43
_reflns_number_total             9290
_reflns_number_gt                8168
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SHELXTL'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
Refinement of F^2^ against ALL reflections.  The weighted R-factor wR and 
goodness of fit S are based on F^2^, conventional R-factors R are based 
on F, with F set to zero for negative F^2^. The threshold expression of 
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is 
not relevant to the choice of reflections for refinement.  R-factors based 
on F^2^ are statistically about twice as large as those based on F, and R- 
factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.0450P)^2^+0.3714P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         9290
_refine_ls_number_parameters     463
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0380
_refine_ls_R_factor_gt           0.0316
_refine_ls_wR_factor_ref         0.0864
_refine_ls_wR_factor_gt          0.0830
_refine_ls_goodness_of_fit_ref   1.028
_refine_ls_restrained_S_all      1.028
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ge1 Ge 0.832476(12) 0.737199(13) 0.255731(10) 0.02025(5) Uani 1 1 d . . .
C1 C 0.90153(12) 0.90834(13) 0.33822(10) 0.0228(3) Uani 1 1 d . . .
H1 H 0.9890 0.9421 0.3366 0.027 Uiso 1 1 calc R . .
C2 C 0.84081(13) 0.98909(13) 0.30746(11) 0.0265(3) Uani 1 1 d . . .
O1 O 0.76161(12) 1.01476(12) 0.34118(11) 0.0437(3) Uani 1 1 d . . .
O2 O 0.88766(11) 1.03178(11) 0.23691(8) 0.0342(3) Uani 1 1 d . . .
C3 C 0.8302(2) 1.09997(19) 0.19280(15) 0.0471(5) Uani 1 1 d . . .
H3A H 0.7476 1.0490 0.1634 0.071 Uiso 1 1 calc R . .
H3B H 0.8738 1.1282 0.1438 0.071 Uiso 1 1 calc R . .
H3C H 0.8299 1.1693 0.2412 0.071 Uiso 1 1 calc R . .
N1 N 0.88566(12) 0.89905(12) 0.43472(9) 0.0256(3) Uani 1 1 d . . .
H1N H 0.9300(18) 0.9427(19) 0.4686(15) 0.031 Uiso 1 1 d . . .
C4 C 0.87080(12) 0.77985(13) 0.45013(10) 0.0225(3) Uani 1 1 d . . .
H4 H 0.9477 0.7654 0.4438 0.027 Uiso 1 1 calc R . .
C5 C 0.84786(12) 0.77393(13) 0.54978(10) 0.0237(3) Uani 1 1 d . . .
C6 C 0.79047(14) 0.84351(14) 0.60071(11) 0.0285(3) Uani 1 1 d . . .
H6 H 0.7640 0.8971 0.5727 0.034 Uiso 1 1 calc R . .
C7 C 0.77185(16) 0.83493(16) 0.69217(12) 0.0340(3) Uani 1 1 d . . .
H7 H 0.7335 0.8834 0.7264 0.041 Uiso 1 1 calc R . .
C8 C 0.80853(16) 0.75655(17) 0.73373(12) 0.0361(4) Uani 1 1 d . . .
H8 H 0.7954 0.7510 0.7962 0.043 Uiso 1 1 calc R . .
C9 C 0.86472(16) 0.68606(17) 0.68359(12) 0.0361(4) Uani 1 1 d . . .
H9 H 0.8896 0.6314 0.7114 0.043 Uiso 1 1 calc R . .
C10 C 0.88456(14) 0.69545(16) 0.59292(11) 0.0306(3) Uani 1 1 d . . .
H10 H 0.9239 0.6475 0.5594 0.037 Uiso 1 1 calc R . .
C11 C 0.77068(12) 0.68131(13) 0.37008(10) 0.0210(3) Uani 1 1 d . . .
C12 C 0.64464(12) 0.67409(13) 0.38178(10) 0.0215(3) Uani 1 1 d . . .
C13 C 0.59264(13) 0.76209(14) 0.39144(11) 0.0264(3) Uani 1 1 d . . .
H13 H 0.6381 0.8426 0.3923 0.032 Uiso 1 1 calc R . .
C14 C 0.47177(14) 0.72981(16) 0.39988(12) 0.0312(3) Uani 1 1 d . . .
H14 H 0.4356 0.7896 0.4076 0.037 Uiso 1 1 calc R . .
C15 C 0.40360(14) 0.61218(16) 0.39721(12) 0.0325(3) Uani 1 1 d . . .
H15 H 0.3212 0.5922 0.4015 0.039 Uiso 1 1 calc R . .
C16 C 0.45487(13) 0.52380(15) 0.38837(12) 0.0295(3) Uani 1 1 d . . .
H16 H 0.4087 0.4434 0.3871 0.035 Uiso 1 1 calc R . .
C17 C 0.57549(13) 0.55544(13) 0.38135(10) 0.0233(3) Uani 1 1 d . . .
C18 C 0.65135(13) 0.48207(13) 0.37322(10) 0.0238(3) Uani 1 1 d . . .
C19 C 0.62529(15) 0.36146(15) 0.37224(12) 0.0324(3) Uani 1 1 d . . .
H19 H 0.5461 0.3119 0.3732 0.039 Uiso 1 1 calc R . .
C20 C 0.71723(17) 0.31469(16) 0.36982(14) 0.0374(4) Uani 1 1 d . . .
H20 H 0.7009 0.2323 0.3686 0.045 Uiso 1 1 calc R . .
C21 C 0.83296(16) 0.38801(16) 0.36920(13) 0.0352(4) Uani 1 1 d . . .
H21 H 0.8951 0.3551 0.3687 0.042 Uiso 1 1 calc R . .
C22 C 0.85963(14) 0.50815(15) 0.36934(11) 0.0280(3) Uani 1 1 d . . .
H22 H 0.9393 0.5573 0.3693 0.034 Uiso 1 1 calc R . .
C23 C 0.76771(13) 0.55575(13) 0.36960(10) 0.0227(3) Uani 1 1 d . . .
C24 C 0.73752(12) 0.73661(13) 0.13602(10) 0.0227(3) Uani 1 1 d . . .
C25 C 0.80292(13) 0.79931(14) 0.07522(11) 0.0252(3) Uani 1 1 d . . .
C26 C 0.74147(15) 0.81160(15) -0.00665(11) 0.0294(3) Uani 1 1 d . . .
H26 H 0.7858 0.8567 -0.0455 0.035 Uiso 1 1 calc R . .
C27 C 0.61790(15) 0.76031(16) -0.03323(12) 0.0323(3) Uani 1 1 d . . .
C28 C 0.55577(14) 0.69345(15) 0.02399(11) 0.0295(3) Uani 1 1 d . . .
H28 H 0.4714 0.6553 0.0058 0.035 Uiso 1 1 calc R . .
C29 C 0.61256(13) 0.67994(13) 0.10756(10) 0.0240(3) Uani 1 1 d . . .
C30 C 0.93807(14) 0.84886(16) 0.09069(12) 0.0317(3) Uani 1 1 d . . .
H30A H 0.9679 0.7841 0.0660 0.048 Uiso 1 1 calc R . .
H30B H 0.9701 0.8822 0.1591 0.048 Uiso 1 1 calc R . .
H30C H 0.9639 0.9124 0.0570 0.048 Uiso 1 1 calc R . .
C31 C 0.55352(19) 0.7717(2) -0.12394(15) 0.0498(5) Uani 1 1 d . . .
H31A H 0.6004 0.8458 -0.1396 0.075 Uiso 1 1 calc R . .
H31B H 0.4745 0.7744 -0.1146 0.075 Uiso 1 1 calc R . .
H31C H 0.5441 0.7023 -0.1763 0.075 Uiso 1 1 calc R . .
C32 C 0.53475(13) 0.60006(16) 0.16037(11) 0.0302(3) Uani 1 1 d . . .
H32A H 0.4992 0.6470 0.2034 0.045 Uiso 1 1 calc R . .
H32B H 0.5835 0.5675 0.1975 0.045 Uiso 1 1 calc R . .
H32C H 0.4710 0.5337 0.1145 0.045 Uiso 1 1 calc R . .
C33 C 0.94920(13) 0.65830(13) 0.21986(11) 0.0239(3) Uani 1 1 d . . .
C34 C 1.07454(13) 0.70820(15) 0.25223(11) 0.0275(3) Uani 1 1 d . . .
C35 C 1.14723(14) 0.64438(16) 0.21887(12) 0.0310(3) Uani 1 1 d . . .
H35 H 1.2312 0.6789 0.2414 0.037 Uiso 1 1 calc R . .
C36 C 1.10181(15) 0.53319(16) 0.15445(12) 0.0324(3) Uani 1 1 d . . .
C37 C 0.97830(15) 0.48280(15) 0.12491(12) 0.0314(3) Uani 1 1 d . . .
H37 H 0.9450 0.4057 0.0814 0.038 Uiso 1 1 calc R . .
C38 C 0.90168(13) 0.54239(14) 0.15741(11) 0.0262(3) Uani 1 1 d . . .
C39 C 1.13796(14) 0.82907(17) 0.32214(14) 0.0391(4) Uani 1 1 d . . .
H39A H 1.2187 0.8344 0.3482 0.059 Uiso 1 1 calc R . .
H39B H 1.0930 0.8381 0.3742 0.059 Uiso 1 1 calc R . .
H39C H 1.1433 0.8932 0.2894 0.059 Uiso 1 1 calc R . .
C40 C 1.18330(19) 0.4684(2) 0.11776(15) 0.0474(5) Uani 1 1 d . . .
H40A H 1.2252 0.5072 0.0720 0.071 Uiso 1 1 calc R . .
H40B H 1.1357 0.3842 0.0862 0.071 Uiso 1 1 calc R . .
H40C H 1.2420 0.4717 0.1713 0.071 Uiso 1 1 calc R . .
C41 C 0.76890(14) 0.47480(15) 0.12489(12) 0.0324(3) Uani 1 1 d . . .
H41A H 0.7558 0.3948 0.0846 0.049 Uiso 1 1 calc R . .
H41B H 0.7343 0.5192 0.0883 0.049 Uiso 1 1 calc R . .
H41C H 0.7304 0.4666 0.1807 0.049 Uiso 1 1 calc R . .
C42 C 0.48053(18) 1.03152(19) 0.36615(16) 0.0474(5) Uani 1 1 d . . .
H42A H 0.4619 1.1049 0.3677 0.071 Uiso 1 1 calc R . .
H42B H 0.5580 1.0517 0.4072 0.071 Uiso 1 1 calc R . .
H42C H 0.4180 0.9749 0.3892 0.071 Uiso 1 1 calc R . .
C43 C 0.48616(18) 0.9757(2) 0.26711(16) 0.0505(5) Uani 1 1 d . . .
H43A H 0.5506 1.0319 0.2442 0.061 Uiso 1 1 calc R . .
H43B H 0.5048 0.9014 0.2652 0.061 Uiso 1 1 calc R . .
O3 O 0.37427(12) 0.94756(13) 0.20673(10) 0.0429(3) Uani 1 1 d . . .
C44 C 0.3709(2) 0.8847(2) 0.11331(17) 0.0578(6) Uani 1 1 d . . .
H44A H 0.3847 0.8086 0.1143 0.069 Uiso 1 1 calc R . .
H44B H 0.4347 0.9338 0.0851 0.069 Uiso 1 1 calc R . .
C45 C 0.2509(2) 0.8582(2) 0.05458(19) 0.0649(7) Uani 1 1 d . . .
H45A H 0.1884 0.8071 0.0815 0.097 Uiso 1 1 calc R . .
H45B H 0.2488 0.8164 -0.0111 0.097 Uiso 1 1 calc R . .
H45C H 0.2371 0.9337 0.0550 0.097 Uiso 1 1 calc R . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
Ge1 0.01591(8) 0.02070(8) 0.02025(8) 0.00204(5) 0.00163(5) 0.00359(5)
C1 0.0189(6) 0.0219(7) 0.0232(7) 0.0031(5) 0.0018(5) 0.0034(5)
C2 0.0262(7) 0.0205(7) 0.0273(7) 0.0034(6) 0.0021(6) 0.0031(6)
O1 0.0424(7) 0.0435(8) 0.0602(9) 0.0246(7) 0.0232(6) 0.0239(6)
O2 0.0449(7) 0.0310(6) 0.0308(6) 0.0121(5) 0.0103(5) 0.0152(5)
C3 0.0683(13) 0.0408(11) 0.0413(10) 0.0189(9) 0.0082(9) 0.0266(10)
N1 0.0274(6) 0.0205(6) 0.0207(6) 0.0006(5) -0.0005(5) 0.0017(5)
C4 0.0184(6) 0.0231(7) 0.0223(7) 0.0037(5) 0.0006(5) 0.0043(5)
C5 0.0193(6) 0.0242(7) 0.0218(7) 0.0028(5) -0.0005(5) 0.0029(5)
C6 0.0309(8) 0.0265(8) 0.0268(7) 0.0056(6) 0.0046(6) 0.0090(6)
C7 0.0405(9) 0.0319(8) 0.0293(8) 0.0051(7) 0.0110(7) 0.0126(7)
C8 0.0413(9) 0.0391(9) 0.0252(8) 0.0083(7) 0.0089(7) 0.0095(7)
C9 0.0412(9) 0.0418(10) 0.0290(8) 0.0132(7) 0.0037(7) 0.0175(8)
C10 0.0302(8) 0.0356(9) 0.0263(8) 0.0066(6) 0.0014(6) 0.0138(7)
C11 0.0182(6) 0.0206(7) 0.0216(6) 0.0035(5) 0.0017(5) 0.0049(5)
C12 0.0193(6) 0.0235(7) 0.0192(6) 0.0042(5) 0.0020(5) 0.0054(5)
C13 0.0252(7) 0.0244(7) 0.0284(7) 0.0056(6) 0.0038(6) 0.0078(6)
C14 0.0276(7) 0.0362(9) 0.0331(8) 0.0085(7) 0.0063(6) 0.0154(7)
C15 0.0213(7) 0.0421(9) 0.0341(8) 0.0110(7) 0.0073(6) 0.0094(6)
C16 0.0228(7) 0.0318(8) 0.0308(8) 0.0108(6) 0.0056(6) 0.0034(6)
C17 0.0226(6) 0.0250(7) 0.0196(6) 0.0058(5) 0.0025(5) 0.0051(5)
C18 0.0245(7) 0.0224(7) 0.0221(7) 0.0051(5) 0.0029(5) 0.0056(5)
C19 0.0346(8) 0.0238(8) 0.0361(9) 0.0085(6) 0.0065(7) 0.0060(6)
C20 0.0460(10) 0.0235(8) 0.0445(10) 0.0106(7) 0.0081(8) 0.0136(7)
C21 0.0378(9) 0.0327(9) 0.0386(9) 0.0080(7) 0.0039(7) 0.0183(7)
C22 0.0258(7) 0.0299(8) 0.0280(8) 0.0059(6) 0.0025(6) 0.0108(6)
C23 0.0239(7) 0.0220(7) 0.0200(6) 0.0033(5) 0.0017(5) 0.0070(5)
C24 0.0203(6) 0.0235(7) 0.0205(6) 0.0011(5) 0.0019(5) 0.0060(5)
C25 0.0259(7) 0.0235(7) 0.0234(7) 0.0018(6) 0.0051(6) 0.0070(6)
C26 0.0333(8) 0.0287(8) 0.0236(7) 0.0055(6) 0.0059(6) 0.0077(6)
C27 0.0339(8) 0.0353(9) 0.0255(8) 0.0055(6) -0.0006(6) 0.0124(7)
C28 0.0236(7) 0.0341(8) 0.0253(7) 0.0018(6) -0.0013(6) 0.0079(6)
C29 0.0214(6) 0.0252(7) 0.0221(7) 0.0013(5) 0.0029(5) 0.0069(5)
C30 0.0247(7) 0.0369(9) 0.0305(8) 0.0089(7) 0.0082(6) 0.0055(6)
C31 0.0448(11) 0.0619(14) 0.0373(10) 0.0207(10) -0.0070(8) 0.0105(10)
C32 0.0203(7) 0.0369(9) 0.0257(7) 0.0047(6) 0.0027(6) 0.0019(6)
C33 0.0201(6) 0.0253(7) 0.0251(7) 0.0066(6) 0.0047(5) 0.0061(5)
C34 0.0218(7) 0.0298(8) 0.0308(8) 0.0090(6) 0.0058(6) 0.0077(6)
C35 0.0214(7) 0.0394(9) 0.0368(9) 0.0151(7) 0.0084(6) 0.0124(6)
C36 0.0338(8) 0.0407(9) 0.0330(8) 0.0146(7) 0.0130(7) 0.0216(7)
C37 0.0349(8) 0.0302(8) 0.0302(8) 0.0047(6) 0.0080(7) 0.0142(7)
C38 0.0255(7) 0.0276(8) 0.0246(7) 0.0059(6) 0.0047(6) 0.0084(6)
C39 0.0186(7) 0.0378(10) 0.0503(11) -0.0007(8) 0.0016(7) 0.0045(6)
C40 0.0484(11) 0.0611(13) 0.0493(11) 0.0157(10) 0.0204(9) 0.0366(10)
C41 0.0273(7) 0.0279(8) 0.0328(8) -0.0025(6) 0.0018(6) 0.0049(6)
C42 0.0396(10) 0.0391(11) 0.0600(13) 0.0172(9) 0.0034(9) 0.0078(8)
C43 0.0385(10) 0.0624(14) 0.0584(13) 0.0223(11) 0.0096(9) 0.0232(10)
O3 0.0370(7) 0.0468(8) 0.0481(8) 0.0122(6) 0.0084(6) 0.0186(6)
C44 0.0613(14) 0.0644(15) 0.0544(13) 0.0127(11) 0.0141(11) 0.0312(12)
C45 0.0755(17) 0.0582(15) 0.0555(14) 0.0082(12) -0.0053(12) 0.0247(13)

_geom_special_details            
; 
All esds (except the esd in the dihedral angle between two l.s. planes) 
are estimated using the full covariance matrix.  The cell esds are taken 
into account individually in the estimation of esds in distances, angles 
and torsion angles; correlations between esds in cell parameters are only 
used when they are defined by crystal symmetry.  An approximate (isotropic) 
treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ge1 C24 1.9800(14) . ?
Ge1 C33 1.9841(15) . ?
Ge1 C1 2.0274(14) . ?
Ge1 C11 2.0410(14) . ?
C1 N1 1.4581(19) . ?
C1 C2 1.501(2) . ?
C2 O1 1.207(2) . ?
C2 O2 1.3361(19) . ?
O2 C3 1.435(2) . ?
N1 C4 1.464(2) . ?
C4 C5 1.515(2) . ?
C4 C11 1.5670(19) . ?
C5 C10 1.396(2) . ?
C5 C6 1.396(2) . ?
C6 C7 1.391(2) . ?
C7 C8 1.382(3) . ?
C8 C9 1.387(3) . ?
C9 C10 1.385(2) . ?
C11 C23 1.509(2) . ?
C11 C12 1.5130(19) . ?
C12 C13 1.387(2) . ?
C12 C17 1.410(2) . ?
C13 C14 1.399(2) . ?
C14 C15 1.388(2) . ?
C15 C16 1.385(2) . ?
C16 C17 1.392(2) . ?
C17 C18 1.457(2) . ?
C18 C19 1.390(2) . ?
C18 C23 1.408(2) . ?
C19 C20 1.390(2) . ?
C20 C21 1.389(3) . ?
C21 C22 1.387(2) . ?
C22 C23 1.396(2) . ?
C24 C29 1.4093(19) . ?
C24 C25 1.417(2) . ?
C25 C26 1.396(2) . ?
C25 C30 1.511(2) . ?
C26 C27 1.388(2) . ?
C27 C28 1.386(2) . ?
C27 C31 1.515(2) . ?
C28 C29 1.398(2) . ?
C29 C32 1.506(2) . ?
C33 C38 1.409(2) . ?
C33 C34 1.415(2) . ?
C34 C35 1.397(2) . ?
C34 C39 1.510(2) . ?
C35 C36 1.379(3) . ?
C36 C37 1.391(2) . ?
C36 C40 1.509(2) . ?
C37 C38 1.399(2) . ?
C38 C41 1.511(2) . ?
C42 C43 1.479(3) . ?
C43 O3 1.426(2) . ?
O3 C44 1.405(3) . ?
C44 C45 1.498(3) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C24 Ge1 C33 107.39(6) . . ?
C24 Ge1 C1 108.42(6) . . ?
C33 Ge1 C1 116.49(6) . . ?
C24 Ge1 C11 127.84(6) . . ?
C33 Ge1 C11 107.23(6) . . ?
C1 Ge1 C11 89.16(6) . . ?
N1 C1 C2 110.46(12) . . ?
N1 C1 Ge1 105.46(9) . . ?
C2 C1 Ge1 112.95(10) . . ?
O1 C2 O2 123.36(15) . . ?
O1 C2 C1 126.03(15) . . ?
O2 C2 C1 110.61(13) . . ?
C2 O2 C3 117.07(14) . . ?
C1 N1 C4 113.97(12) . . ?
N1 C4 C5 111.46(12) . . ?
N1 C4 C11 109.66(12) . . ?
C5 C4 C11 112.97(11) . . ?
C10 C5 C6 118.13(14) . . ?
C10 C5 C4 119.16(14) . . ?
C6 C5 C4 122.71(13) . . ?
C7 C6 C5 120.45(15) . . ?
C8 C7 C6 120.65(16) . . ?
C7 C8 C9 119.51(16) . . ?
C10 C9 C8 119.93(16) . . ?
C9 C10 C5 121.32(16) . . ?
C23 C11 C12 102.54(11) . . ?
C23 C11 C4 112.41(12) . . ?
C12 C11 C4 114.21(11) . . ?
C23 C11 Ge1 112.95(9) . . ?
C12 C11 Ge1 117.63(9) . . ?
C4 C11 Ge1 97.63(9) . . ?
C13 C12 C17 119.64(13) . . ?
C13 C12 C11 130.55(13) . . ?
C17 C12 C11 109.81(12) . . ?
C12 C13 C14 118.61(14) . . ?
C15 C14 C13 121.37(15) . . ?
C16 C15 C14 120.48(15) . . ?
C15 C16 C17 118.54(15) . . ?
C16 C17 C12 121.33(14) . . ?
C16 C17 C18 129.86(14) . . ?
C12 C17 C18 108.81(12) . . ?
C19 C18 C23 121.16(14) . . ?
C19 C18 C17 130.36(14) . . ?
C23 C18 C17 108.44(13) . . ?
C18 C19 C20 118.77(15) . . ?
C21 C20 C19 120.25(16) . . ?
C22 C21 C20 121.40(16) . . ?
C21 C22 C23 119.01(15) . . ?
C22 C23 C18 119.35(14) . . ?
C22 C23 C11 130.37(13) . . ?
C18 C23 C11 110.24(12) . . ?
C29 C24 C25 118.52(13) . . ?
C29 C24 Ge1 125.51(11) . . ?
C25 C24 Ge1 115.97(10) . . ?
C26 C25 C24 119.45(14) . . ?
C26 C25 C30 116.94(14) . . ?
C24 C25 C30 123.53(14) . . ?
C27 C26 C25 122.32(15) . . ?
C28 C27 C26 117.55(14) . . ?
C28 C27 C31 121.00(16) . . ?
C26 C27 C31 121.38(16) . . ?
C27 C28 C29 122.47(14) . . ?
C28 C29 C24 119.49(14) . . ?
C28 C29 C32 116.79(13) . . ?
C24 C29 C32 123.69(13) . . ?
C38 C33 C34 118.02(14) . . ?
C38 C33 Ge1 116.42(10) . . ?
C34 C33 Ge1 125.55(12) . . ?
C35 C34 C33 119.71(15) . . ?
C35 C34 C39 116.13(14) . . ?
C33 C34 C39 124.16(14) . . ?
C36 C35 C34 122.53(15) . . ?
C35 C36 C37 117.62(14) . . ?
C35 C36 C40 121.11(16) . . ?
C37 C36 C40 121.27(17) . . ?
C36 C37 C38 121.93(16) . . ?
C37 C38 C33 120.08(14) . . ?
C37 C38 C41 116.78(14) . . ?
C33 C38 C41 123.12(13) . . ?
O3 C43 C42 109.79(17) . . ?
C44 O3 C43 112.28(16) . . ?
O3 C44 C45 109.09(19) . . ?

_diffrn_measured_fraction_theta_max 0.871
_diffrn_reflns_theta_full        29.43
_diffrn_measured_fraction_theta_full 0.871
_refine_diff_density_max         0.493
_refine_diff_density_min         -0.326
_refine_diff_density_rms         0.053

#===END